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Inorg. Chem., 2009, 48, 2639-2651.

X. �Y. Tang, R. �X. Yuan, Z. �G. Ren, H. �X. Li, Y. Zhang, J. �P. Lang*,

发布者:系统管理员  发布时间:2013-08-07  浏览次数:0

 

Reactions of [Hg(Tab)2](PF6)2 (1) with phen, 2,2’-bipy, py, N-Meim, N-iPrim, en, eten, tmen, dap, or dpt gave rise to a family of cationic mercury(II) thiolate complexes. In all these structures, the original trans configuration of the [Hg(Tab)2]2+ dication of 1 is changed via rotation and/or switching of the two Tab species along the S-Hg-S line together with the rotation of the phenyl groups of the Tab ligands. The results may provide an interesting insight into mimicking the interactions of the Hg(Cys)2 linear species in Hg-MerR and Hg-MT with various N-donor ligands.

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