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Inorg. Chem., 2006, 45, 2568-2580.

J. �X. Chen, W. �H. Zhang, X. �Y. Tang, Z. �G. Ren, Y. Zhang, J. �P. Lang*,

发布者:系统管理员  发布时间:2013-08-07  浏览次数:0

 

Reactions of Hg(OAc)2 with 2 equiv of TabHPF6 [TabH ) 4-(trimethylammonio)benzenethiol] in MeCN/MeOH afforded a mononuclear linear complex [Hg(Tab)2](PF6)2 (1). By using 1 as a precursor, a new family of mercury(II) zwitterionic thiolate complexes (2-10) were prepared and characterized by elemental analysis, IR spectra, UV-vis spectra, 1HNMR, and single-crystal X-ray crystallography. Compound 9 consists of two [Tab-Tab]2+ dications and one [Hg3Cl10]4- tetraanion. The facile approach to the construction of 2-8 and 10 from 1 may be applicable to the mimicking of a coordination sphere of the Hg sites of metallothioneins.

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