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Chem. Commun., 2013, 49, 2682-2684.

发布者:系统管理员  发布时间:2013-08-07  浏览次数:0

 

D. Liu, J. �P. Lang*, B. F. Abrahams, Stepwise ligand transformations through [2+2] photodimerization and hydrothermal in situ oxidation reactions, Chem. Commun., 2013, 49, 2682-2684.

The SCSC transformation of a 1D polymer [Cd(1,3-bdc)(4-spy)2]n produced a 2D polymer [Cd(1,3-bdc)(4-spy)(HT-ppcb)0.5]n through the [2+2] photodimerization reaction. Hydrothermal reactions of HT-ppcb with CdCl2, 1,3-H2bdc and H2O2 afforded another 2D polymer {[Cd(H2O)(1,3-bdc)(bpbpf)]・H2O}n in which HT-ppcb underwent an in situ oxidation to form a unique furan-based ligand bpbpf.

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