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Chem. Commun., 2013, 49, 4836-4838.

发布者:系统管理员  发布时间:2013-08-07  浏览次数:0

 

Z. �H. Wei, C. �Y. Ni, L. �K. Zhou, H. �X. Li, Z. �G. Ren, J. �P. Lang*, Z. �R. Sun*, [PyH][{TpMo(μ3-S)3Cu3(μ3-S′)}4(μ12-I)]: A Unique Tetracubane-Type Mo/Cu/S Cluster Formed from the S-S Cleavage and the Iodide Templation and its Enhanced NLO Performance, Chem. Commun., 2013, 49, 4836-4838.

Reactions of [Et4N][TpMoS(S4)] with three equiv. of CuI in MeCN or in pyridine gave rise to one dicubane and one tetracubane anionic clusters [Et4N]2[{TpMo(μ3-S)3Cu3I}2(μ-I){Cu(μ-I)2(μ4-I)2}] and [PyH][{TpMo(μ3-S)4Cu3}4(μ12-I)], and their third-order nonlinear optical (NLO) responses were greatly enhanced relative to that of the precursor.

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