Issue 47, 2007
From the journal:

Chemical Communications

Unique formation of two high-nuclearity metallamacrocycles from a mononuclear complex [Zn(dmpzdtc)2] (dmpzdtc = 3,5-dimethylpyrazole-1-dithiocarboxylate) via CS2 elimination†

Hong-Xi Li,a   Hua-Zhou Wu,a   Wen-Hua Zhang,a   Zhi-Gang Ren,a   Yong Zhanga  and  Jian-Ping Lang*ab  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Jiangsu, P. R. China
E-mail: jplang@suda.edu.cn
Fax: 86-512-65880089

b State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, Jiangsu, P. R. China

Abstract

Dissolution of a mononuclear complex [Zn(dmpzdtc)2] in BrCH2CH2Br or DMF saturated with water followed by CS2 elimination led to the formation of two unique high-nuclearity metallamacrocyclic complexes, [Zn4(μ-dmpz)6(μ-OH)2]2 and [Zn4(μ-dmpz)6(μ-OH)2]4.

Graphical abstract: Unique formation of two high-nuclearity metallamacrocycles from a mononuclear complex [Zn(dmpzdtc)2] (dmpzdtc = 3,5-dimethylpyrazole-1-dithiocarboxylate) via CS2 elimination

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Article information

DOI
https://doi.org/10.1039/B710787K
Article type
Communication
Submitted
16 Jul 2007
Accepted
10 Sep 2007
First published
27 Sep 2007

Chem. Commun., 2007, 5052-5054

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Unique formation of two high-nuclearity metallamacrocycles from a mononuclear complex [Zn(dmpzdtc)2] (dmpzdtc = 3,5-dimethylpyrazole-1-dithiocarboxylate) via CS2 elimination

H. Li, H. Wu, W. Zhang, Z. Ren, Y. Zhang and J. Lang, Chem. Commun., 2007, 5052 DOI: 10.1039/B710787K

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